Browsing Research Articles (Chemistry) by Issue Date
Now showing items 21-40 of 221
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A new vanadium (III) complex of 2,6-Bis(3,5-diphenylpyrazol- 1-ylmethyl)pyridine as a catalyst for ethylene polymerization
(MDPI, 2013)The tridentate ligand 2,6-bis(3,5-diphenylpyrazol-1-ylmethyl)pyridine, abbreviated as 2,6-[(3,5-ph2pz-CH2)2-py], a new pyridine-pyrazole derivative, was prepared from 2,6-bis(bromomethyl)pyridine and 3,5-diphenylpyrazole. ... -
Marrubiin
(MDPI, 2013)The ethno-medicinal approach to drug discovery represents one of the most important sources of new and safe therapeutic agents to the challenges confronting modern medicine and daily life. Many of the traditionally ... -
Effect of ni core structure on the electrocatalytic activity of pt-ni/c in methanol oxidation.
(MDPI, 2013)Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C), were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms ... -
Salicylaldiminato chromium complex supported on chemically modified silica as highly active catalysts for the oxidation of cyclohexene
(Elsevier, 2013)Immobilization of chromium complexes on modified silica support was achieved via two different synthetic routes using 3-aminopropyl triethoxysilane (APTS) as a linking group. The FTIR spectra, elemental and solid-state NMR ... -
Synthesis of an ordered mesoporous carbon with graphitic characteristics and its application for dye adsorption
(Springer, 2013)An ordered mesoporous carbon (OMC) was prepared by a chemical vapor deposition technique using liquid petroleum gas (LPG) as the carbon source. During synthesis, LPG was effectively adsorbed in the ordered mesopores of ... -
Imino-phospine palladium (II) and platinum (II) complexes: Synthesis, molecular structures and evaluation as antitumor agents
(Elsevier, 2013)The imino-phosphine ligands L1 and L2 were prepared via condensation reaction of 2-(diphenylphosphino) benzaldehyde with substituted anilines and obtained in very good yields. An equimolar reaction of L1 and L2 with ... -
Oxidation of benzoin catalyzed by oxovanadium (IV) schiff base complexes
(Chemistry Central, 2013)BACKGROUND: The oxidative transformation of benzoin to benzil has been accomplished by the use of a wide variety of reagents or catalysts and different reaction procedures. The conventional oxidizing agents yielded ... -
Synthesis and electronic properties of Alkyl- and alkyloxy-cucuminoids
(Elsevier, 2013)Two series of p‐alkyl‐ and p‐alkoxy‐substituted curcuminoids were synthesized. The validity of the proposed structures was checked on the basis of their high resolution mass spectra as well as NMR, IR and electronic ... -
Chemical, mineralogical and morphological changes in weathered coal fly ash: A case study of a brine impacted wet ash dump
(Elsevier, 2013)The mobility of species in coal fly ash (FA), co-disposed with brine using a wet ash handling system, from a coal fired power generating utility has been investigated. The study was conducted in order to establish if the ... -
Comparison of CO2 capture by ex-situ accelerated carbonation and in in-situ naturally weathered coal fly ash
(Elsevier, 2013)Natural weathering at coal power plants ash dams occurs via processes such as carbonation, dissolution, co-precipitation and fluid transport mechanisms which are responsible for the long-term chemical, physical and geochemical ... -
Laboratory study on the mobility of major species in fly ash–brine co-disposal systems: up-flow percolation test
(Springer Verlag, 2013)Apart from the generation of fly ash, brine (hyper-saline wastewater) is also a waste material generated in South African power stations as a result of water re-use. These waste materials contain major species such as Al, ... -
Synthesis of zeolites from coal fly ash using mine waters
(Elsevier, 2013)In this study mine waters obtained from coal mining operations in South Africa were used as a substitute for pure water during the synthesis of zeolites from South African coal fly ash. Procedures that had been optimized ... -
Few-layer binder free graphene modified mercury film electrode for trace metal analysis by square wave anodic stripping voltammetry
(ESG, 2013)A binding agent free graphene modified glassy carbon electrode in combination with an in situ plated mercury film electrode (Gr-GC-HgFE) was used as a highly sensitive electrochemical platform for the determination of Zn2+, ... -
Imino-quinolyl palladium(II) and platinum(II) complexes: synthesis, characterization, molecular structures and cytotoxic effect
(Elsevier, 2013)Imino-quinolyl ligands L1-L5 were synthesized by condensation reactions and obtained in good yields. Reactions of the ligands with either PdCl2(cod) or K2[PtCl4] gave the corresponding palladium(II) and platinum(II) complexes ... -
Selenium functionalized carbon for high dispersion of platinumeruthenium nanoparticles and its effect on the electrocatalytic oxidation of methanol
(Elsevier, 2013)Using selenium functionalized carbon as supports, platinumeruthenium nanoparticles were highly dispersed on the carbon surface, and showed improved electrochemical properties for methanol electrooxidation. The method ... -
A review of pharmaceuticals and endocrine-disrupting compounds: sources, effects, removal, and detections
(Springer, 2013)There are growing concerns about the increasing trends of emerging micropollutants in the environment due to their potential negative impacts on natural ecosystems and humans. This has attracted attention from both ... -
Platinum overlaid PdCulr/C: an Improved Methanol Oxidation Elextrocatalyst
(ESG, 2013)A platinum overlaid PdCuIr/C (Pt-PdIrCu/C) anodic catalyst for direct methanol fuel cell was prepared by a two-step reduction method. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) results show that the ... -
Phylogeny of Southern African and Australasian Wahlenbergioids (Campanulaceae) based on ITS and trnL-F sequence data: implications for a reclassification
(Aspt American Society of Plant Taxonomists, 2013)The Campanulaceae: Wahlenbergioideae currently comprises 15 genera, one of which, Wahlenbergia, is widespread over the southern continents. Southern Africa is the region with maximum wahlenbergioid diversity with 12 genera ... -
Dichlorido-[(2-diphenylphosphino-benzylidene)-2-methylphenylen-amine]palladium( II) acetonitrile monosolvate
(International Union of Crystallography, 2013)The title imino–phosphine compound, [PdCl2(C26H22NP)] - CH3CN, was prepared by reaction of N-[2-(diphenylphosphanyl) benzylidene]-2-methylaniline with dichlorido(cycloocta- 1,5-diene)palladium(II) in dry CH2Cl2. The ... -
Antibacterial and anti-inflammatory effects of Syzygium jambos L. (Alston) and isolated compounds on acne vulgaris
(BioMed Central, 2013)Acne vulgaris is a chronic skin disorder leading to inflammation as a result of the production of reactive oxygen species due to the active involvement of Propionibacterium acnes (P. acnes) in the infection site of the ...