Browsing Faculty of Natural Sciences by Subject "Fly ash"
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Musingarimi, Wicleffe; Tuffin, I. Marla; Cowan, Donald A. (Academy of Science of South Africa, 2010)[more][less]
Abstract: An arsenic resistant Bacillus sp. UWC was isolated from fly ash acid mine drainage (FA-AMD) neutralised solids. A genomic library was prepared and screened in an arsenic sensitive mutant Escherichia coli strain for the presence of arsenic resistance (ars) genes. Sequence analysis of a clone conferring resistance to both sodium arsenite and sodium arsenate revealed homologues to the arsR (regulatory repressor), arsB (membrane located arsenite pump), arsC (arsenate reductase), arsD (second regulatory repressor and a metallochaperone) and arsA (ATPase) genes from known arsenic resistance operons. The Bacillus sp. UWC arsRBCDA genes were shown to be arranged in an unusual manner with the arsDA genes immediately downstream of arsC. URI: http://hdl.handle.net/10566/160 Files in this item: 1
MusingarimiCharacterisation2010.PDF (566.6Kb) -
Babajide, Omotola; Petrik, Leslie; Musyoka, Nicholas; Amigun, Bamikole; Ameer, Farouk (Slovnaft VÚRUP, 2010)[more][less]
Abstract: South Africa is largely dependent on the combustion of coal for electricity production; Eskom’s coalfired power stations consume approximately 109 million tons of coal per annum, producing around 25 million tons of ash, to supply the bulk (93%) of South Africa’s electricity. The management of this fly ash has been a concern with various approaches for its beneficial use being investigated. This work presents the results of transesterification reaction using sunflower oil as feedstock with methanol and class F fly ash catalyst derived from a coal fly ash dump in South Africa to produce methyl esters (biodiesel). The fly ash based catalyst was prepared using the wet impregnation procedure with different loadings of potassium. This was characterized by powder X-ray diffraction (XRD), FTIR spectroscopy. The XRD patterns obtained indicated that the structure of the support gradually deformed with an increase in the loading and the extent of decomposition of KNO3 varied with the amount of loading. The influence of various reactions parameters such as loading amount of active components, methanol: oil ratio, reaction time, temperature and catalyst deactivation was investigated. The fly ash based catalyst loaded with 5% wt KNO3 at a reaction temperature of 160ºC exhibited maximum oil conversion (86.13%). The biodiesel synthesized was tested and important fuel properties of the methyl esters (Biodiesel) compared well with ASTM biodiesel standard URI: http://hdl.handle.net/10566/574 Files in this item: 1
BabajideBiodieselProduction2010.pdf (597.5Kb)
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