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    Optimisation of electrophoretic deposition parameters for gas diffusion electrodes in high temperature polymer electrolyte membrane fuel cells

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    Felix_Optimasation of electrophoretic_2013.pdf (1.641Mb)
    Date
    2013
    Author
    Felix, Cecil
    Jao, Ting-Chu
    Pasupathi, Sivakumar
    Pollet, Bruno G.
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    Abstract
    Electrophoretic deposition (EPD) method was used to fabricate gas diffusion electrodes (GDEs) for high temperature polymer electrolyte membrane fuel cells (HT PEMFC). Parameters related to the catalyst suspension and the EPD process were studied. Optimum suspension conditions are obtained when the catalyst particles are coated with Nafion® ionomer and the pH is adjusted to an alkaline range of about 8 e10. These suspensions yield good stability with sufficient conductivity to form highly porous catalyst layers on top of the gas diffusion layers (GDLs). GDEs were fabricated by applying various electric field strengths of which 100 V cm-1 yields the best membrane electrode assembly (MEA) performance. Compared to an MEA fabricated by the traditional hand sprayed (HS) method, the EPD MEA shows superior performance with a peak power increase of about 73% at similar platinum (Pt) loadings. Electrochemical Impedance Spectroscopy (EIS) analysis shows lower charge transfer resistance for the MEA fabricated via the EPD method compared to the HS MEA. The EPD GDE exhibits a greater total pore area (22.46 m2 g-1) compared to the HS GDE (13.43 m2 g-1) as well as better dispersion of the Pt particles within the catalyst layer (CL).
    URI
    http://dx.doi.org/10.1016/j.jpowsour.2013.06.006
    http://hdl.handle.net/10566/3369
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    • Research Articles (SAIAMC) [38]

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