| dc.contributor.author | Motswainyana, William M. | |
| dc.contributor.author | Onani, Martin O. | |
| dc.contributor.author | Jacobs, Jeroen | |
| dc.contributor.author | van Meervelt, Luc | |
| dc.date.accessioned | 2013-10-13T20:11:22Z | |
| dc.date.available | 2013-10-13T20:11:22Z | |
| dc.date.issued | 2012 | |
| dc.identifier.citation | Motswainyana, W.M., et al. (2012). Dichlorido-[2-(2,6-diethylphenyl)iminomethylquinoline-N,N’]palladium(II) acetonitrile monosolvate. Acta Cryst. C68, m356–m358 | en_US |
| dc.identifier.issn | 0108-2701 | |
| dc.identifier.uri | http://hdl.handle.net/10566/751 | |
| dc.description.abstract | The title complex, [PdCl2(C20H20N2)] CH3CN, was synthesized
by the reaction of 2-[(2,6-diethylphenyl)iminomethyl]quinoline
with dichlorido(cycloocta-1,5-diene)palladium(II) in dry
CH2Cl2. The PdII ion is coordinated by two N atoms of the
bidentate quinoline ligand and by two chloride anions,
generating a distorted square-planar coordination geometry
around the metal centre. There is a detectable trans influence
for the chloride ligands. The crystal packing is characterized
by – stacking between the quinoline rings. The use of
acetonitrile as the crystallization solvent was essential for
obtaining good-quality crystals. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | International Union of Crystallography | en_US |
| dc.rights | Copyright International Union of Crystallography. This file may be freely used for educational purposes, as long as it is not altered in any way. Acknowledgement of the authors and the source is required. | |
| dc.source.uri | http://dx.doi.org/10.1107/S0108270112045970 | |
| dc.title | Dichlorido-[2-(2,6-diethylphenyl)iminomethylquinoline-N,N’]palladium(II) acetonitrile monosolvate | en_US |
| dc.type | Article | en_US |
| dc.privacy.showsubmitter | false | |
| dc.status.ispeerreviewed | true | |
| dc.description.accreditation | Web of Science | en_US |
