| dc.contributor.author | Motswainyana, William M. | |
| dc.contributor.author | Onani, Martin O. | |
| dc.contributor.author | Jacobs, Jeroen | |
| dc.contributor.author | van Meervelt, Luc | |
| dc.date.accessioned | 2013-10-13T20:31:28Z | |
| dc.date.available | 2013-10-13T20:31:28Z | |
| dc.date.issued | 2013 | |
| dc.identifier.citation | Motswainyana, W.M., et al. (2013). Dichlorido-[(2-diphenylphosphino-benzylidene)-2-methylphenylen-amine]palladium( II) acetonitrile monosolvate. Acta Cryst. C69, 209–211 | en_US |
| dc.identifier.issn | 0108-2701 | |
| dc.identifier.uri | http://hdl.handle.net/10566/752 | |
| dc.description.abstract | The title imino–phosphine compound, [PdCl2(C26H22NP)] -
CH3CN, was prepared by reaction of N-[2-(diphenylphosphanyl)
benzylidene]-2-methylaniline with dichlorido(cycloocta-
1,5-diene)palladium(II) in dry CH2Cl2. The PdII cation
is coordinated by the P and N atoms of the bidentate chelating
ligand and by two chloride anions, generating a distorted
square-planar coordination geometry. There is a detectable
trans influence for the chloride ligands. The methyl group
present in this structure has an influence on the crystal
packing. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | International Union of Crystallography | en_US |
| dc.rights | Copyright International Union of Crystallography. This file may be freely used for educational purposes, as long as it is not altered in any way. Acknowledgement of the authors and the source is required. | |
| dc.source.uri | http://dx.doi.org/10.1107/S0108270113002333 | |
| dc.title | Dichlorido-[(2-diphenylphosphino-benzylidene)-2-methylphenylen-amine]palladium( II) acetonitrile monosolvate | en_US |
| dc.type | Article | en_US |
| dc.privacy.showsubmitter | false | |
| dc.status.ispeerreviewed | true | |
| dc.description.accreditation | Web of Science | en_US |
