Chemistry
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Fabrication of polyoxometalate-modified palladium–nickel/reduced graphene oxide alloy catalysts for enhanced oxygen reduction reaction activity
(Royal Society of Chemistry, 2021)Designing advanced nanocatalysts for effectively catalyzing the oxygen reduction reaction (ORR) is of great importance for practical applications of direct methanol fuel cells (DMFCs). In this work, the reduced graphene ... -
A quarter century of marine biodiscovery in Algoa bay, South Africa
(Journal of Natural Products, 2023)Algoa Bay, the largest crenulate bay on the south-eastern coast of South Africa, is currently one of the most well-studied marine ecosystems in southern Africa. A plethora of endemic marine invertebrates inhabits the benthic ... -
Zinc(ii) complex of (Z)-4-((4-Nitrophenyl)Amino)Pent-3-en-2-one, a potential antimicrobial agent: synthesis, characterization, antimicrobial screening, DFT calculation and docking study
(Chemical Society of Ethiopia, 2023)Herein, the synthesis and characterizations of (Z)-4-((4-nitrophenyl)amino)pent-3-en-2-one (HL) ligand and its Zn(II) complex are reported. The compounds were characterized using elemental and thermogravimetric (TGA) ... -
Antimicrobial activity of the secondary metabolites isolated from a South African red seaweed, laurencia corymbosa
(MDPI, 2023)South Africa’s highly diverse marine biota includes several endemic marine red algae of the Laurencia genus. Cryptic species and morphological variability make the taxonomy of Laurencia plant challenging, and a record of ... -
Fabrication and characterization of electrospun waste polyethylene terephthalate blended with chitosan: A potential single-use material
(MDPI, 2023)Textile single-use products are dominantly used for hygiene and personal care, many of which are non-biodegradable and are frequently discarded into sewerage systems, thus causing blockages. Thus, there is a need to move ... -
Effects of film thickness of ALD-deposited Al2O3, ZrO2 and HfO2 nano-layers on the corrosion resistance of Ti(N,O)-coated stainless steel
(MDPI, 2023)The goal of this stydy was to explore the potential of the enhanced corrosion resistance of Ti(N,O) cathodic arc evaporation-coated 304L stainless steel using oxide nano-layers deposited by atomic layer deposition (ALD). ... -
Spray‐pyrolyzed Cd‐substituted kesterite thin‐films for photovoltaic applications: Post annealing conditions and property studies
(Elsevier, 2023)Kesterite materials were investigated for their suitability as absorber layers for thin-film photovoltaic cells. Thin- films of copper cadmium zinc tin sulfide (Cu2CdxZn1-xSnS4) were prepared by spray pyrolysis on soda-lime ... -
Nanostructured silicon derived from an agricultural residue bagasse ash via magnesiothermic reduction method
(MDPI, 2023)This study presents the magnesiothermic reduction of silica into silicon. This reduction process occurs at a lower reaction temperature than its carbothermal counterpart. Furthermore, silica was extracted from sugarcane ... -
Effects of Film Thickness of ALD-Deposited Al2O3, ZrO2 and HfO2 Nano-Layers on the Corrosion Resistance of Ti(N,O)-Coated Stainless Steel
(MDPI, 2023)The goal of this stydy was to explore the potential of the enhanced corrosion resistance of Ti(N,O) cathodic arc evaporation-coated 304L stainless steel using oxide nano-layers deposited by atomic layer deposition (ALD). ... -
Selectivity of oxygen evolution reaction on carbon cloth-supported δ-mno2 nanosheets in electrolysis of real seawater
(Molecules, 2023)Electrolysis of seawater using solar and wind energy is a promising technology for hydrogen production which is not affected by the shortage of freshwater resources. However, the competition of chlorine evolution reactions ... -
Photovoltaic efficiencies of microwave and Cu2ZnSnS4 (CZTS) superstrate solar cells
(Materials Today Sustainability, 2023)Organic and inorganic materials such as perovskites, copper indium gallium diselenide, cadmium telluride, and copper zinc tin sulfide/selenide (CZTS/Se) have been employed to capture unlimited sunlight through the photovoltaic ... -
Efficient Long-range Active Galactic Nuclei (AGNs) Feedback Affects the Low-redshift Lyα Forest
(American Astronomical Society, 2023)Active galactic nuclei (AGNs) feedback models are generally calibrated to reproduce galaxy observables such as the stellar mass function and the bimodality in galaxy colors. We use variations of the AGN feedback implementations ... -
Nanostructured europium-doped layered lithium manganese oxide as a prospective cathode material for aqueous lithium-ion battery
(Elsevier, 2023)As the world moves to greener and renewable energy generation technologies, scientific researchers are facing a great challenge of concurrently developing energy storage materials with a low production cost, environmentally ... -
Materials, components, assembly and performance of flexible polymer electrolyte membrane fuel cell: A review
(Elsevier, 2023)With emerging demand of potable and wearable electronic devices, reliable and flexible energy suppliers are inevitable. Polymer electrolyte membrane fuel cells (PEMFCs) attract great attention due to high energy density and ... -
Synthesis of bimetallic FeMn nanoparticles using rooibos tea extract: characterization and application
(Springer, 2023)Bimetallic FeMn nanoparticles based on a ferromanganese wad were successfully synthesized employing an entirely green approach. South African rooibos tea (RTea) extract was used as an environmentally friendly reducing and ... -
Novel heterojunction superstrate Cu2ZnInS4−x (CZIS) thin film kesterite solar cell with vertical arrays of hexagonal ZnO nanorods window layer
(Elsevier, 2022-11-24)Quaternary Cu2ZnInS4−x (CZIS) thin films have been prepared by a facile and cheap sol-gel spin coating technique. Low-temperature solution-based methods were used to fabricate a heterojunction solar cell in the superstrate ... -
Development of Unsupported Ru and Ni Based Oxides with Enhanced Performance for the Oxygen Evolution Reaction in Acidic Media
(Springer, 2023)The high cost of catalyst materials suitable for the oxygen evolution reaction (OER) in polymer electrolyte membrane water electrolyzers (PEMWE) is still a major hurdle that needs overcoming before commercial PEMWE can ... -
Polyaniline entrapped water-dispersible 3mpa-znse quantum dots and their application for the development of an enzymatic electrochemical nanobiosensor for the detection of 17β-estradiol, an endocrine-disrupting compound
(SpringerLink, 2023)17β-estradiol is used as a growth and fertility stimulant in the agronomic sector to induce fertility and manipulate reproductive characteristics in animals. However, unintended or unregulated distribution and exposure to ... -
Setting the baseline for the modelling of Kesterite solar cells: The case study of tandem application
(Elsevier, 2023)The Kesterite solar cells research landscape is at a crossroad and despite a much improved understanding of the limitations of this class of materials, the current performance deficit contrasts with the several other thin ... -
Synthesis and characterisation of a polysulfone-polyvinyl alcohol hydrogelic material
(ESG, 2016)Hydrogels are flexible materials that have found a niche in membrane science owing to their ability to absorb water without dissolving. The synthesis of polyvinyl alcohol-polysulfone hydrogel in the presence of N-hydroxy ...