Browsing Chemistry by Issue Date
Now showing items 41-60 of 271
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Synthesis of zeolites from coal fly ash using mine waters
(Elsevier, 2013)In this study mine waters obtained from coal mining operations in South Africa were used as a substitute for pure water during the synthesis of zeolites from South African coal fly ash. Procedures that had been optimized ... -
Few-layer binder free graphene modified mercury film electrode for trace metal analysis by square wave anodic stripping voltammetry
(ESG, 2013)A binding agent free graphene modified glassy carbon electrode in combination with an in situ plated mercury film electrode (Gr-GC-HgFE) was used as a highly sensitive electrochemical platform for the determination of Zn2+, ... -
Imino-quinolyl palladium(II) and platinum(II) complexes: synthesis, characterization, molecular structures and cytotoxic effect
(Elsevier, 2013)Imino-quinolyl ligands L1-L5 were synthesized by condensation reactions and obtained in good yields. Reactions of the ligands with either PdCl2(cod) or K2[PtCl4] gave the corresponding palladium(II) and platinum(II) complexes ... -
Selenium functionalized carbon for high dispersion of platinumeruthenium nanoparticles and its effect on the electrocatalytic oxidation of methanol
(Elsevier, 2013)Using selenium functionalized carbon as supports, platinumeruthenium nanoparticles were highly dispersed on the carbon surface, and showed improved electrochemical properties for methanol electrooxidation. The method ... -
A review of pharmaceuticals and endocrine-disrupting compounds: sources, effects, removal, and detections
(Springer, 2013)There are growing concerns about the increasing trends of emerging micropollutants in the environment due to their potential negative impacts on natural ecosystems and humans. This has attracted attention from both ... -
Platinum overlaid PdCulr/C: an Improved Methanol Oxidation Elextrocatalyst
(ESG, 2013)A platinum overlaid PdCuIr/C (Pt-PdIrCu/C) anodic catalyst for direct methanol fuel cell was prepared by a two-step reduction method. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) results show that the ... -
Amphibious Horses: Beings in the Littoral and Liminal Contact Zones
(2013)Horses galloping in littoral zones are represented as embodying wildness, freedom and a prelapsarian quality. Roy Campbell’s ‘The Horses of the Camargue’ includes themes which recur in texts about littoral horses: the ... -
Phylogeny of Southern African and Australasian Wahlenbergioids (Campanulaceae) based on ITS and trnL-F sequence data: implications for a reclassification
(Aspt American Society of Plant Taxonomists, 2013)The Campanulaceae: Wahlenbergioideae currently comprises 15 genera, one of which, Wahlenbergia, is widespread over the southern continents. Southern Africa is the region with maximum wahlenbergioid diversity with 12 genera ... -
Dichlorido-[(2-diphenylphosphino-benzylidene)-2-methylphenylen-amine]palladium( II) acetonitrile monosolvate
(International Union of Crystallography, 2013)The title imino–phosphine compound, [PdCl2(C26H22NP)] - CH3CN, was prepared by reaction of N-[2-(diphenylphosphanyl) benzylidene]-2-methylaniline with dichlorido(cycloocta- 1,5-diene)palladium(II) in dry CH2Cl2. The ... -
Antibacterial and anti-inflammatory effects of Syzygium jambos L. (Alston) and isolated compounds on acne vulgaris
(BioMed Central, 2013)Acne vulgaris is a chronic skin disorder leading to inflammation as a result of the production of reactive oxygen species due to the active involvement of Propionibacterium acnes (P. acnes) in the infection site of the ... -
Waste minimization protocols for the process of synthesizing zeolites from South African coal fly ash
(MDPI, 2013)Production of a high value zeolite from fly ash has been shown to be an avenue for the utilization of South African fly ash which presently constitutes a huge disposal problem. The synthesis of zeolites Na-P1 and analcime ... -
Actuation behaviour of a derivatized pyrrole accordion type polymer
(ESG, 2014)A monomer (Phenazine-2,3-diimino(pyrrole-2-yl)–PDP) derived from the condensation reaction between 2,3-diaminophenazine and a pyrrole derivative has been synthesized as a hinge molecule in the design of a zig-zag polymer. ... -
A review of combined advanced oxidation technologies for the removal of organic pollutants from water
(Springer Verlag, 2014)Water pollution through natural and anthropogenic activities has become a global problem causing short-and long-term impact on human and ecosystems. Substantial quantity of individual or mixtures of organic pollutants enter ... -
An unusual 2,3-secotaraxerene and other cytotoxic triterpenoids from pleiocarpa pycnantha (apocynaceae) leaves collected from Nigeria
(MDPI, 2014)Three known triterpenoids, namely ursolic acid (1), and the 27-E- and 27-Z-pcoumaric esters of ursolic acid (compounds 2, 3), were isolated together with a new triterpene 2,3-seco-taraxer-14-en-2,3-lactone [pycanocarpine ... -
Electrochemically reduced graphene oxide pencil-graphite in situ plated bismuth-film electrode for the determination of trace metals by anodic stripping voltammetry
(ESG, 2014)An electrochemical platform was developed based on a pencil-graphite electrode (PGE) modified with electrochemically reduced graphene oxide (ERGO) sheets and in conjunction with an in situ plated bismuth-film (ERGO-PG-BiE). ... -
Carcinoembryonic antigen immunosensor developed with organoclay nanogold composite film
(ESG, 2014)Organoclay nanogold composite were prepared using gold nanoparticles and the natural Cameroonian clay grafted with amino organosilane. The functionnalization of clay provided abundant amino group to assemble gold nanoparticles. ... -
Application of nano zinc oxide (nZnO) for the removal of triphenyltin chloride (TPT) from dockyard wastewater
(Water Research Commission, 2014)The use of triphenyltin chloride (TPT), a persistent organic pollutant, as a biocide has led to serious contamination of the marine environment. The potential of nano zinc oxide (nZnO) for the removal of TPT from contaminated ... -
The potential of leucosidea sericea against propionibacterium acnes
(Elsevier, 2014)The present study reports on the potential of Leucosidea sericea addressing acne vulgaris. Four known compounds namely phytol acetate, triacontanol, phytol and alpha kosin and one new compound namely, (E)-3,7,11,15-tetra ... -
A fumonisins immunosensor based on polyanilino-carbon nanotubes doped with palladium telluride quantum dots
(MDPI, 2015)An impedimetric immunosensor for fumonisins was developed based on poly(2,5-dimethoxyaniline)-multi-wall carbon nanotubes doped with palladium telluride quantum dots onto a glassy carbon surface. The composite was assembled ... -
Application on gold nanoparticles-dotted 4-nitrophenylazo graphene in a label-free impedimetric deoxynivalenol immunosensor
(MDPI, 2015)In this paper, we report a new concept to construct a label-free electrochemical inhibition-based immunosensor for the detection of the mycotoxin deoxynivalenol (DON) in cereal samples. The electrochemical impedance ...