Research Articles (Chemistry)
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An electrochemically active green synthesized polycrystalline NiO/MgO catalyst: Use in photo-catalytic applications
(Elsevier, 2018)For many years, research scientists have aided communities in their tremendous efforts towards environmental remediation. Due to their high physical and chemical stability, metal oxide nanoparticles (NPs) have been used as ... -
Synthesis and electronic properties of Alkyl- and alkyloxy-cucuminoids
(Elsevier, 2013)Two series of p‐alkyl‐ and p‐alkoxy‐substituted curcuminoids were synthesized. The validity of the proposed structures was checked on the basis of their high resolution mass spectra as well as NMR, IR and electronic ... -
Oxidation of benzoin catalyzed by oxovanadium (IV) schiff base complexes
(Chemistry Central, 2013)BACKGROUND: The oxidative transformation of benzoin to benzil has been accomplished by the use of a wide variety of reagents or catalysts and different reaction procedures. The conventional oxidizing agents yielded ... -
Few-layer binder free graphene modified mercury film electrode for trace metal analysis by square wave anodic stripping voltammetry
(ESG, 2013)A binding agent free graphene modified glassy carbon electrode in combination with an in situ plated mercury film electrode (Gr-GC-HgFE) was used as a highly sensitive electrochemical platform for the determination of Zn2+, ... -
Bioaccumulation of total mercury in the earthworm Eisenia andrei
(SpringerOpen, 2016)Earthworms are a major part of the total biomass of soil fauna and play a vital role in soil maintenance. They process large amounts of plant and soil material and can accumulate many pollutants that may be present in ... -
The production of hydrogen through the use of a 77 wt% Pd 23 wt% Ag membrane water gas shift reactor
(Elsevier, 2016)Hydrogen as an energy carrier has the potential to decarbonize the energy sector. This work presents the application of a palladium-silver (PdeAg) membrane-based reactor. The membrane reactor which is made from PdeAg ... -
Antibacterial activities of bacteria isolated from the marine sponges Isodictya compressa and Higginsia bidentifera collected from Algoa Bay, South Africa
(MDPI AG, 2017)Due to the rise inmulti-drug resistant pathogens and other diseases, there is renewed interest in marine sponge endosymbionts as a rich source of natural products (NPs). The South African marine environment is rich in ... -
Effect of nanoparticle (Pd, Pd/Pt, Ni) deposition on high temperature hydrogenation of Ti-V alloys in gaseous flow containing CO
(Elsevier B.V., 2017)The hydrogenation properties of Ti-V hydrides coated with nanoparticles have been studied in gaseous mixtures of argon and hydrogen with and without additions of 1% CO. Nanoparticles of Pd, Ni, and co-deposited Pd/Pt with ... -
Cytotoxic, cytostatic and HIV-1 PR inhibitory activities of the soft coral litophyton arboreum
(MDPI, 2013)Bioassay-guided fractionation using different chromatographic and spectroscopic techniques in the analysis of the Red Sea soft coral Litophyton arboreum led to the isolation of nine compounds; sarcophytol M (1), alismol ... -
Potential broad spectrum inhibitors of the coronavirus 3CLpro: a virtual screening and structure-based drug design study
(MDPI, 2015)Human coronaviruses represent a significant disease burden; however, there is currently no antiviral strategy to combat infection. The outbreak of severe acute respiratory syndrome (SARS) in 2003 and Middle East respiratory ... -
Platinum overlaid PdCulr/C: an Improved Methanol Oxidation Elextrocatalyst
(ESG, 2013)A platinum overlaid PdCuIr/C (Pt-PdIrCu/C) anodic catalyst for direct methanol fuel cell was prepared by a two-step reduction method. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) results show that the ... -
Amorphous Pt@dCu/CNT catalyst for methanol elextrooxidation
(South African Chemical Institute (SACI), 2013)A multi-walled carbon nanotube-supported, Pt decorated nano-sized amorphous PdCu alloy cores (denoted as Pt@PdCu/CNT) catalyst with lower Pt loading is synthesized via a galvanic displacement reaction. The structure is ... -
Effect of ni core structure on the electrocatalytic activity of pt-ni/c in methanol oxidation.
(MDPI, 2013)Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C), were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms ... -
Aptameric recognition-modulated electroactivity of poly(4-styrenesolfonic acid)-doped polyaniline films for single-shot detection of tetrodotoxin
(MDPI, 2015)The work being reported is the first electrochemical sensor for tetrodotoxin (TTX). It was developed on a glassy carbon electrodes (C) that was modified with poly(4-styrenesolfonic acid)-doped polyaniline film (PANI/PSSA). ... -
Testing of eight medicinal plant extracts in combination with kresoxim-methyl for integrated control of botrytis cinerea in apples
(MDPI, 2015)Botrytis cinerea is a fungus that causes gray mold on many fruit crops. Despite the availability of a large number of botryticides, the chemical control of gray mold has been hindered by the emergence of resistant strains. ... -
Exploration of scaffolds from natural products with antiplasmodial activities, currently registered antimalarial drugs and public malarial screen data
(MDPI, 2016)In light of current resistance to antimalarial drugs, there is a need to discover new classes of antimalarial agents with unique mechanisms of action. Identification of unique scaffolds from natural products with in vitro ... -
Marrubiin
(MDPI, 2013)The ethno-medicinal approach to drug discovery represents one of the most important sources of new and safe therapeutic agents to the challenges confronting modern medicine and daily life. Many of the traditionally ... -
Acylphloroglucinol derivatives from the South African helichrysum niveum and their biological activities
(MDPI, 2015)Abstract: Phytochemical investigation of aerial parts of Helichrysum niveum (H. niveum) using different chromatographic methods including semi-preparative HPLC afforded three new (1–3) and six known (4–10) acylphloroglucinols ... -
Inhibition of oxidative stress and skin aging-related enzymes by prenylated chalcones and other flavonoids from helichrysum teretifolium
(MDPI, 2015)Ten flavonoid-related structures viz. heliteretifolin (1), isoxanthohumol (2), 2',4',6'-trihydroxy-3'-prenylchalcone (3), isoglabranin (4), glabranin (5), 7-methoxyisoglabranin (6), quercetin (7), 4'-methoxyquercetin ... -
Metallo-graphene nanocomposite electrocatalytic platform for the determination of toxic metal ions
(MDPI, 2011)A Nafion-Graphene (Nafion-G) nanocomposite solution in combination with an in situ plated mercury film electrode was used as a highly sensitive electrochemical platform for the determination of Zn2+, Cd2+, Pb2+ and Cu2+ ...
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