Browsing Research Articles (SAIAMC) by Issue Date
Now showing items 1-20 of 79
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Components for PEM fuel cells: An overview
(Trans Tech Publications, 2010)Fuel cells, as devices for direct conversion of the chemical energy of a fuel into electricity by electrochemical reactions, are among the key enabling technologies for the transition to a hydrogen-based economy. Among ... -
Pt decorated amorphous RuIr alloys as high efficiency electrocatalyst for methanol oxidation
(The Electrochemical Society, 2012)This study focuses primarily on improving the utilization and activity of anodic catalysts for methanol electro-oxidation. The Direct Methanol Fuel Cell (DMFC) anodic catalyst, a carbon supported Pt decorated amorphous ... -
Synthesis and optimisation of IrO2 electrocatalysts by Adams fusion method for solid polymer electrolyte electrolysers
(Bentham Science Publishers, 2012)IrO2 as an anodic electrocatalyst for the oxygen evolution reaction (OER) in solid polymer electrolyte (SPE) electrolysers was synthesised by adapting the Adams fusion method. Optimisation of the IrO2 electrocatalyst was ... -
Effects of heat treatment on the catalytic activity and methanol tolerance of carbon-supported platinum alloys
(Springer, 2012)This work studies the effect of heat treatment of carbon-dispersed platinum and platinum alloys on its methanol tolerance and catalytic activity as gas diffusion electrodes for oxygen reduction reaction (ORR) in acid medium. ... -
Synthesis, characterisation and evaluation of IrO2 based binary metal oxide electrocatalysts for oxygen evolution reaction
(Electochemical Society Inc., 2012)IrO2, IrxRu1-xO2, IrxSnx-1O2 and IrxTax-1O2 (1 ≥ x ≥ 0.7) were synthesized, characterised and evaluated as electrocatalysts for the oxygen evolution reaction in solid polymer electrolyte electrolysers. The electrocatalysts ... -
Thermal conductivity and temperature profiles of the micro porous layers used for the polymer electrolyte membrane fuel cell
(Elsevier, 2013)The thermal conductivity and the thickness change with pressure of several different micro porous layers (MPL) used for the polymer electrolyte membrane fuel cell (PEMFC) were measured. The MPL were made with different ... -
Characterization and activity test of commercial Ni/Al2O3, Cu/ZnO/Al2O3 and prepared NieCu/Al2O3 catalysts for hydrogen production from methane and methanol fuels
(Elsevier, 2013)In this study, methane and methanol steam reforming reactions over commercial Ni/Al2O3, commercial Cu/ZnO/Al2O3 and prepared NieCu/Al2O3 catalysts were investigated. Methane and methanol steam reforming reactions catalysts ... -
Fuel cell-battery hybrid powered light electric vehicle (golf cart): Influence of fuel cell on the driving performance
(Elsevier, 2013)A light electric vehicle (golf cart, 5 kW nominal motor power) was integrated with a commercial 1.2 kW PEM fuel cell system, and fuelled by compressed hydrogen (two composite cylinders, 6.8 L/300 bar each). Comparative ... -
Membrane electrode assemblies with low noble metal loadings for hydrogen production from solid polymer electrolyte water electrolysis
(Elsevier, 2013)High performance membrane electrode assemblies (MEAs) with low noble metal loadings (NMLs) were developed for solid polymer electrolyte (SPE) water electrolysis. The electro- chemical and physical characterization of the ... -
Palygorskite hybridized carbon nanocomposite as a high-performance electrocatalyst support for formic acid oxidation
(South African Chemical Institute (SACI), 2013)A nanocomposite, in which acid-treated palygorskite was hybridized with carbon, was prepared and designed as an efficient support for electrocatatlysts. Pd nanoparticles were deposited on the hybrid support as an ... -
Effect of the structure of Ni nanoparticles on the electrocatalytic activity of Ni@Pd/C for formic acid oxidation
(Elsevier, 2013)Ni@Pd/C catalysts were synthesized, using Ni/C with different crystalline structures prepared with various ligands. A series of characterizations were performed by transmission electron microscopy, X-ray diffraction, X-ray ... -
Montmorillonite modified by CNx supported Pt for methanol oxidation
(Elsevier, 2013)A composite support based on nature clay, i.e. montmorillonite (MMT), shows great promise as support materials for Pt electrocatalyst for the methanol oxidation reaction in fuel cell anodes. The reported composite support ... -
Nitrogen-doped carbon coated ZeO2 as a support to Pt nanoparticles in the oxygen reduction reaction
(Elsevier, 2013)A new nitrogen-doped carbon (CNx) support for Pt electrocatalysts was prepared by carbonizing polypyrrole on the surface of ZrO2 (ZrO2@CNx) at high temperature. Well-dispersed Pt nanoparticles were easily formed on the ... -
Biomass-derived activated carbon as high-performance non-precious electrocatalyst for oxygen reduction
(Royal Society of Chemistry, 2013)A new type of Fe and N doped carbon material is synthesized by pyrolyzing ferric chloride doped egg white (EW) and the proposed synthetic route is easy, green, and low-cost. In addition, the as-prepared sample exhibits ... -
Synthesis of carbon-supported PdSn–SnO2 nanoparticles with different degrees of interfacial contact and enhanced catalytic activities for formic acid oxidation
(Royal Society of Chemistry, 2013)The conjunction of the PdSn alloy and SnO2 is of interest for improving catalytic activity in formic acid oxidation (FAO). Here, we report the synthesis of PdSn–SnO2 nanoparticles and a study of their catalytic FAO ... -
Graphite-anchored lithium vanadium oxide as anode of lithium ion battery
(Elsevier, 2013)Graphite-anchored lithium vanadium oxide (Li1.1V0.9O2) has been synthesized via a “one-pot” in situ method. The effects of the synthesis conditions, such as the ratio of reaction components and calcination temperature, ... -
Supported 3-D Pt nanostructures: the straightforward synthesis and enhanced electrochemical performance for methanol oxidation in an acidic medium
(Springer, 2013)Noble metal nanostructures with branched morphologies [i.e., 3-D Pt nanoflowers (NFs)] by tridimensionally integrating onto conductive carbon materials are proved to be an efficient and durable electrocatalysts for methanol ... -
Magnesium–carbon hydrogen storage hybrid materials produced by reactive ball milling in hydrogen
(Elsevier, 2013)Time-resolved studies uncovered kinetics and mechanism of Mg–hydrogen interactions during High energy reactive ball milling in hydrogen (HRBM) in presence of various types of carbon, including graphite (G), activated carbon ... -
Optimization of gas diffusion electrode for polybenzimidazole-based high temperature proton exchange membrane fuel cell: Evaluation of polymer binders in catalyst layer
(Elsevier, 2013)Gas diffusion electrodes (GDEs) prepared with various polymer binders in their catalyst layers (CLs) were investigated to optimize the performance of phosphoric acid doped polybenzimidazole (PBI)-based high temperature ... -
A new route to control texture of materials: Nanostructured ZnFe2O4 photoelectrodes
(2013)Studies were conducted to investigate the influence of deposition solution composition (methanol ≤ the deposition solvent ≤ ethanol) on their physical and chemical properties that matters in the aerosol formation and ...