South African Institute for Advanced Materials Chemistry (SAIAMC): Recent submissions
Now showing items 41-60 of 76
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Optimization of gas diffusion electrode for polybenzimidazole-based high temperature proton exchange membrane fuel cell: Evaluation of polymer binders in catalyst layer
(Elsevier, 2013)Gas diffusion electrodes (GDEs) prepared with various polymer binders in their catalyst layers (CLs) were investigated to optimize the performance of phosphoric acid doped polybenzimidazole (PBI)-based high temperature ... -
Magnesium–carbon hydrogen storage hybrid materials produced by reactive ball milling in hydrogen
(Elsevier, 2013)Time-resolved studies uncovered kinetics and mechanism of Mg–hydrogen interactions during High energy reactive ball milling in hydrogen (HRBM) in presence of various types of carbon, including graphite (G), activated carbon ... -
Hydrogen absorption study of high-energy reactive ball milled Mg composites with palladium additives
(Elsevier, 2013)Hydrogenation behaviour, structure, morphology and dehydrogenation/re-hydrogenation performances of Mg–Pd nanocomposites prepared by high-energy reactive ball milling in H2 (HRBM) of Mg in the presence of amorphous and ... -
Fuel cell-battery hybrid powered light electric vehicle (golf cart): Influence of fuel cell on the driving performance
(Elsevier, 2013)A light electric vehicle (golf cart, 5 kW nominal motor power) was integrated with a commercial 1.2 kW PEM fuel cell system, and fuelled by compressed hydrogen (two composite cylinders, 6.8 L/300 bar each). Comparative ... -
Validation of an externally oil-cooled 1 kWel HT-PEMFC stack operating at various experimental conditions
(Elsevier, 2013)The performance of 1 kWel 48-cell HT-PEMFC at various experimental conditions is presented, particularly at several CO concentrations (up to 1.0%). Polarization curves measured at various anode (1.0-2.5) and cathode (1.6-4.0) ... -
Membrane electrode assemblies with low noble metal loadings for hydrogen production from solid polymer electrolyte water electrolysis
(Elsevier, 2013)High performance membrane electrode assemblies (MEAs) with low noble metal loadings (NMLs) were developed for solid polymer electrolyte (SPE) water electrolysis. The electro- chemical and physical characterization of the ... -
A new route to control texture of materials: Nanostructured ZnFe2O4 photoelectrodes
(2013)Studies were conducted to investigate the influence of deposition solution composition (methanol ≤ the deposition solvent ≤ ethanol) on their physical and chemical properties that matters in the aerosol formation and ... -
Montmorillonite modified by CNx supported Pt for methanol oxidation
(Elsevier, 2013)A composite support based on nature clay, i.e. montmorillonite (MMT), shows great promise as support materials for Pt electrocatalyst for the methanol oxidation reaction in fuel cell anodes. The reported composite support ... -
Biomass-derived activated carbon as high-performance non-precious electrocatalyst for oxygen reduction
(Royal Society of Chemistry, 2013)A new type of Fe and N doped carbon material is synthesized by pyrolyzing ferric chloride doped egg white (EW) and the proposed synthetic route is easy, green, and low-cost. In addition, the as-prepared sample exhibits ... -
Palygorskite hybridized carbon nanocomposite as a high-performance electrocatalyst support for formic acid oxidation
(South African Chemical Institute (SACI), 2013)A nanocomposite, in which acid-treated palygorskite was hybridized with carbon, was prepared and designed as an efficient support for electrocatatlysts. Pd nanoparticles were deposited on the hybrid support as an ... -
Effect of the structure of Ni nanoparticles on the electrocatalytic activity of Ni@Pd/C for formic acid oxidation
(Elsevier, 2013)Ni@Pd/C catalysts were synthesized, using Ni/C with different crystalline structures prepared with various ligands. A series of characterizations were performed by transmission electron microscopy, X-ray diffraction, X-ray ... -
Nitrogen-doped carbon coated ZeO2 as a support to Pt nanoparticles in the oxygen reduction reaction
(Elsevier, 2013)A new nitrogen-doped carbon (CNx) support for Pt electrocatalysts was prepared by carbonizing polypyrrole on the surface of ZrO2 (ZrO2@CNx) at high temperature. Well-dispersed Pt nanoparticles were easily formed on the ... -
Nanoparticulate TiO2-promoted PtRu/C catalyst for methanol oxidation: TiO2 nanoparticles promoted PtRu/C catalyst for MOR
(Springer, 2013)To improve the electrocatalytic properties of PtRu/C in methanol electrooxidation, nanoparticulate TiO2-promoted PtRu/C catalysts were prepared by directly mixing TiO2 nanoparticles with PtRu/C. Using cyclic voltammetry, ... -
CNx-modified Fe3O4 as Pt nanoparticle support for the oxygen reduction reaction
(Springer, 2013)A novel electrocatalyst support material, nitrogendoped carbon (CNx)-modified Fe3O4 (Fe3O4-CNx), was synthesized through carbonizing a polypyrrole-Fe3O4 hybridized precursor. Subsequently, Fe3O4-CNx-supported Pt (Pt/Fe3O4-CNx) ... -
Selenium-functionalized carbon as a support for platinum nanoparticles with improved electrochemical properties for the oxygen reduction reaction and CO tolerance
(Electrochemical Society, 2013)Using selenium-functionalized carbon as supports, platinum nanoparticles were uniformly dispersed on the carbon surface, and showed improved electrochemical properties for the oxygen reduction reaction. At the same time ... -
Supported 3-D Pt nanostructures: the straightforward synthesis and enhanced electrochemical performance for methanol oxidation in an acidic medium
(Springer, 2013)Noble metal nanostructures with branched morphologies [i.e., 3-D Pt nanoflowers (NFs)] by tridimensionally integrating onto conductive carbon materials are proved to be an efficient and durable electrocatalysts for methanol ... -
RuxNb1-xO2 catalyst for the oxygen evolution reaction in proton exchange membrane water electrolysers
(Elsevier, 2013)Bimetallic catalyst system of ruthenium oxide (RuO2) and niobium oxide (Nb2O5) was prepared using the Adams method and the hydrolysis method. Physical and electrochemical characterizations of the catalysts were studied ... -
Poisoning-tolerant metal hydride materials and their application for hydrogen separation from CO2/CO containing gas mixtures
(Elsevier, 2013)Metal hydride materials offer attractive solutions in addressing problems associated with hydrogen separation and purification from waste flue gases. However, a challenging problem is the deterioration of hydrogen charging ... -
Application of surface-modified metal hydrides for hydrogen separation from gas mixtures containing carbon dioxide and monoxide
(Elsevier, 2013)Application of surface-modified MH material for H2 separation using temperature/pressure swing absorption–desorption was studied. The substrate alloy had the following composition LaNi3.55Co0.75Al0.4-Mn0.3, and the surface ... -
Characterization and activity test of commercial Ni/Al2O3, Cu/ZnO/Al2O3 and prepared NieCu/Al2O3 catalysts for hydrogen production from methane and methanol fuels
(Elsevier, 2013)In this study, methane and methanol steam reforming reactions over commercial Ni/Al2O3, commercial Cu/ZnO/Al2O3 and prepared NieCu/Al2O3 catalysts were investigated. Methane and methanol steam reforming reactions catalysts ...