South African Institute for Advanced Materials Chemistry (SAIAMC): Recent submissions
Now showing items 61-76 of 76
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Enhanced drug loading capacity of polypyrrole nanowire network for confrolled drug release
(Elsevier, 2013)For a conducting polymer (CP) based drug release system, drug loading is often accomplished by a doping process, in which drug is incorporated into polymer as dopant. Therefore, the drug loading capacity is relatively low ... -
Pt-Sn/C as a possible methanol-tolerant cathode catalyst for DMFC
(Springer Verlag, 2013)An effective method was developed for preparing highly dispersed nano-sized Pt–Sn/C electrocatalyst synthesised by a modified polyol reduction method. From XRD patterns, the Pt–Sn/C peaks shifted slightly to lower 2θ angles ... -
Enhanced performance of polybenzimidazole-based high temperature proton exchange membrane fuel cell with gas diffusion electrodes prepared by automatic catalyst spraying under irradiation technique
(Elsevier, 2013)Gas diffusion electrodes (GDEs) prepared by a novel automatic catalyst spraying under irradiation (ACSUI) technique are investigated for improving the performance of phosphoric acid (PA)-doped polybenzimidazole (PBI) high ... -
Optimisation of electrophoretic deposition parameters for gas diffusion electrodes in high temperature polymer electrolyte membrane fuel cells
(Elsevier, 2013)Electrophoretic deposition (EPD) method was used to fabricate gas diffusion electrodes (GDEs) for high temperature polymer electrolyte membrane fuel cells (HT PEMFC). Parameters related to the catalyst suspension and the ... -
High temperature (HT) polymer electrolyte membrande fuel cells (PEMFC) - A review
(Elsevier, 2013)One possible solution of combating issues posed by climate change is the use of the High Temperature (HT) Polymer Electrolyte Membrane (PEM) Fuel Cell (FC) in some applications. The typical HT-PEMFC operating temperatures ... -
Synthesis of carbon-supported PdSn–SnO2 nanoparticles with different degrees of interfacial contact and enhanced catalytic activities for formic acid oxidation
(Royal Society of Chemistry, 2013)The conjunction of the PdSn alloy and SnO2 is of interest for improving catalytic activity in formic acid oxidation (FAO). Here, we report the synthesis of PdSn–SnO2 nanoparticles and a study of their catalytic FAO ... -
Pt decorated amorphous RuIr alloys as high efficiency electrocatalyst for methanol oxidation
(The Electrochemical Society, 2012)This study focuses primarily on improving the utilization and activity of anodic catalysts for methanol electro-oxidation. The Direct Methanol Fuel Cell (DMFC) anodic catalyst, a carbon supported Pt decorated amorphous ... -
Graphite-anchored lithium vanadium oxide as anode of lithium ion battery
(Elsevier, 2013)Graphite-anchored lithium vanadium oxide (Li1.1V0.9O2) has been synthesized via a “one-pot” in situ method. The effects of the synthesis conditions, such as the ratio of reaction components and calcination temperature, ... -
Ethanol oxidation activity and structure of carbon-supported Pt-modified PdSn-SnO2 influenced by different stabilizers
(Elsevier, 2013)PdSn-SnO2 nanoparticles supported on Vulcan XC-72 carbon were synthesized by chemical reduction in the presence of three different stabilizing agents: ethylene diamine tetra-acetic acid (EDTA), sodium citrate (Nacitrate) ... -
Nafion-stabilised platinum nanoparticles supported on titanium nitride: An efficient and durable electrocatalyst for phosphoric acid based polymer electrolyte fuel cells
(Elsevier, 2013)Nafion derived platinum nanoparticles were produced and successfully anchored on titanium nitride (TiN) support (Pt/TiN) and its suitability for phosphoric acid based polymer electrolyte membrane fuel cells is reported. ... -
Beef-derived mesoporous carbon as highly efficient support for PtRuIr electrocatalysts and their high activity for CO and methanol oxidation
(SACI, 2014)In this work, a low-cost and nitrogen-containing carbon with mesoporous pores and high surface area was synthesized by carbonizing a natural biomass precursor, i.e. beef. It is found that the prepared material has excellent ... -
The use of metal hydrides in fuel cell applications
(Elsevier B.V., 2017)This paper reviews state-of-the-art developments in hydrogen energy systems which integrate fuel cells with metal hydride-based hydrogen storage. The 187 reference papers included in this review provide an overview of all ... -
Synthesis, characterisation and evaluation of IrO2 based binary metal oxide electrocatalysts for oxygen evolution reaction
(Electochemical Society Inc., 2012)IrO2, IrxRu1-xO2, IrxSnx-1O2 and IrxTax-1O2 (1 ≥ x ≥ 0.7) were synthesized, characterised and evaluated as electrocatalysts for the oxygen evolution reaction in solid polymer electrolyte electrolysers. The electrocatalysts ... -
Synthesis and optimisation of IrO2 electrocatalysts by Adams fusion method for solid polymer electrolyte electrolysers
(Bentham Science Publishers, 2012)IrO2 as an anodic electrocatalyst for the oxygen evolution reaction (OER) in solid polymer electrolyte (SPE) electrolysers was synthesised by adapting the Adams fusion method. Optimisation of the IrO2 electrocatalyst was ... -
Effects of heat treatment on the catalytic activity and methanol tolerance of carbon-supported platinum alloys
(Springer, 2012)This work studies the effect of heat treatment of carbon-dispersed platinum and platinum alloys on its methanol tolerance and catalytic activity as gas diffusion electrodes for oxygen reduction reaction (ORR) in acid medium. ... -
Components for PEM fuel cells: An overview
(Trans Tech Publications, 2010)Fuel cells, as devices for direct conversion of the chemical energy of a fuel into electricity by electrochemical reactions, are among the key enabling technologies for the transition to a hydrogen-based economy. Among ...