Amorphous Pt@dCu/CNT catalyst for methanol elextrooxidation

Abstract

A multi-walled carbon nanotube-supported, Pt decorated nano-sized amorphous PdCu alloy cores (denoted as Pt@PdCu/CNT) catalyst with lower Pt loading is synthesized via a galvanic displacement reaction. The structure is examined using X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrochemical activity of the Pt@PdCu/CNT catalyst is tested by cyclic voltammogrametry (CV) and compared to that of PtRu/CNT catalysts. The results show that amorphous Pt@PdCu/CNT catalyst exhibits better electro-catalytic performances for methanol oxidation than its crystalline counterpart.