Browsing Research Articles (Chemistry) by Title
Now showing items 1-20 of 145
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1D NiHPO4 nanotubes prepared using dissolution equilibrium as bifunctional electrocatalyst for high-efficiency water splitting
(Journal of Power Sources, 2021)In this work, one-dimensional NiHPO4 nanotubes are successfully fabricated on nickel foam by hydrothermal reaction, in which a dissolution equilibrium between phosphates is controlled by tuning the proportion of the mixed ... -
4-Oxatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione derivatives as NMDA receptor- and VGCC blockers with neuroprotective potential
(MDPI, 2020)The impact of excitotoxicity mediated by N-methyl-D-aspartate (NMDA) receptor overactivation and voltage gated calcium channel (VGCC) depolarization is prominent among the postulated processes involved in the development ... -
Abundance of no3 derived organo-nitrates and their importance in the atmosphere
(MPDI, 2021)The chemistry of the nitrate radical and its contribution to organo-nitrate formation in the troposphere has been investigated using a mesoscale 3-D chemistry and transport model, WRFChem-CRI. The model-measurement ... -
Actuation behaviour of a derivatized pyrrole accordion type polymer
(ESG, 2014)A monomer (Phenazine-2,3-diimino(pyrrole-2-yl)–PDP) derived from the condensation reaction between 2,3-diaminophenazine and a pyrrole derivative has been synthesized as a hinge molecule in the design of a zig-zag polymer. ... -
Acylation of anisole with benzoyl chloride over rapidly synthesized fly ash–based hbea zeolite
(Frontiers Media, 2021)Stable HBEA zeolite with high surface area and strong acid sites was synthesized from coal fly ash–based silica extract via indirect hydrothermal synthesis. The rapid HBEA hydrothermal crystallization times of 8, 10, and ... -
Acylphloroglucinol derivatives from the South African helichrysum niveum and their biological activities
(MDPI, 2015)Abstract: Phytochemical investigation of aerial parts of Helichrysum niveum (H. niveum) using different chromatographic methods including semi-preparative HPLC afforded three new (1–3) and six known (4–10) acylphloroglucinols ... -
Advances in nanotechnology towards development of silver nanoparticle-based wound-healing agents
(MPDI, 2021)Since antiquity, silver-based therapies have been used in wound healing, wound care and management of infections to provide adequate healing. These therapies are associated with certain limitations, such as toxicity, ... -
Alpha-glucosidase and alpha-amylase inhibitory activities, molecular docking, and antioxidant capacities of salvia aurita constituents
(MPDI, 2020)Diabetes mellitus (DM) is one of the most dangerous metabolic diseases with a high rate of mortality worldwide. It is well known that insulin resistance and deficiency in insulin production from pancreatic β-cells are the ... -
Amorphous Pt@dCu/CNT catalyst for methanol elextrooxidation
(South African Chemical Institute (SACI), 2013)A multi-walled carbon nanotube-supported, Pt decorated nano-sized amorphous PdCu alloy cores (denoted as Pt@PdCu/CNT) catalyst with lower Pt loading is synthesized via a galvanic displacement reaction. The structure is ... -
Analyzing chemical data in more than two dimensions: A tutorial on factor and cluster analysis
(Journal of chemical education, 1990)This tutorial is intended to introduce factor and cluster analysis at a level that will afford a senior student-and the practicing chemist, for that matter-some insights into the workings of the computer packages employing ... -
Antibacterial activities of bacteria isolated from the marine sponges Isodictya compressa and Higginsia bidentifera collected from Algoa Bay, South Africa
(MDPI AG, 2017)Due to the rise inmulti-drug resistant pathogens and other diseases, there is renewed interest in marine sponge endosymbionts as a rich source of natural products (NPs). The South African marine environment is rich in ... -
Anticorrosion coated stainless steel as durable support for C-N-TiO2 photo catalyst layer
(MDPI, 2020)The development of durable photocatalytic supports resistant in harsh environment has become challenging in advanced oxidation processes (AOPs) focusing on water and wastewater remediation. In this study, stainless steel ... -
Application on gold nanoparticles-dotted 4-nitrophenylazo graphene in a label-free impedimetric deoxynivalenol immunosensor
(MDPI, 2015)In this paper, we report a new concept to construct a label-free electrochemical inhibition-based immunosensor for the detection of the mycotoxin deoxynivalenol (DON) in cereal samples. The electrochemical impedance ... -
Aptameric recognition-modulated electroactivity of poly(4-styrenesolfonic acid)-doped polyaniline films for single-shot detection of tetrodotoxin
(MDPI, 2015)The work being reported is the first electrochemical sensor for tetrodotoxin (TTX). It was developed on a glassy carbon electrodes (C) that was modified with poly(4-styrenesolfonic acid)-doped polyaniline film (PANI/PSSA). ... -
Atmospheric bromoform at Cape Point, South Africa: an initial fixed-point data set on the African continent
(EGU, 2018)Bromoform mixing ratios in marine air were measured at Cape Point Global Atmospheric Watch Station, South Africa. This represents the first such bromoform data set recorded at this location. Manual daily measurements were ... -
The Behaviour of Rare Earth Elements from South African Coal Fly Ash during Enrichment Processes: Wet, Magnetic Separation and Zeolitisation
(MDPI, 2021)Rare earth elements (REEs) are essential raw materials in a variety of industries including clean energy technologies such as electric vehicles and wind turbines. This places an ever-increasing demand on global rare earth ... -
The behaviour of rare earth elements from South African coal fly ash during enrichment processes: wet, magnetic separation and zeolitisation
(MDPI, 2021)are earth elements (REEs) are essential raw materials in a variety of industries including clean energy technologies such as electric vehicles and wind turbines. This places an ever-increasing demand on global rare earth ... -
Binderless zeolite monoliths production with sacrificial biopolymers
(Elsevier, 2021)3D printing has emerged as an attractive way of formulating structured adsorbents, as it imparts lower manufacturing costs compared to hydraulic extrusion while also allowing for unprecedented geometric control. However, ... -
Bioaccumulation of total mercury in the earthworm Eisenia andrei
(SpringerOpen, 2016)Earthworms are a major part of the total biomass of soil fauna and play a vital role in soil maintenance. They process large amounts of plant and soil material and can accumulate many pollutants that may be present in ... -
Bis(ferrocenylimine)palladium(II) and platinum(II) complexes: synthesis, molecular structures and evaluation as antitumor agents
(Elsevier, 2012)Compounds (ferrocenyl-2-furylmethyl)imine (L1), (ferrocenyl-2-thiophenemethyl)imine (L2) and (ferrocenyl-2-thiopheneethyl)imine (L3) were synthesized by condensation reactions and obtained in very good yields. Reactions ...
