Browsing Research Articles (Chemistry) by Title
Now showing items 131-150 of 221
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Microscopic, spectroscopic, and electrochemical characterization of novel semicrystalline poly(3-hexylthiophene)-based dendritic star copolymer
(MDPI, 2022)In this study, electron-donating semicrystalline generation 1 poly(propylene thiophenoimine)- co-poly(3-hexylthiophene) star copolymer, G1PPT-co-P3HT was chemically prepared for the first time. Copolymerization was ... -
Microscopic, spectroscopic, and electrochemical characterization of novel semicrystalline poly(3-hexylthiophene)-based dendritic star copolymer
(MDPI, 2022): In this study, electron-donating semicrystalline generation 1 poly(propylene thiophenoimine)- co-poly(3-hexylthiophene) star copolymer, G1PPT-co-P3HT was chemically prepared for the first time. Copolymerization was ... -
Microwave-assisted synthesis of schiff base metal–ligand complexes with copper and nickel centres for electrochemical in vitro sensing of nitric oxide in an aqueous solution
(MDPI, 2022)Nitric oxide (NO), the smallest signalling molecule known in the human body, keeps blood vessels dilated, controls blood pressure, and has numerous other health regulatory effects. The use of Schiff base complexes ... -
Mn nanoparticles encapsulated within mesoporous helical n-doped carbon nanotubes as highly active air cathode for zinc–air batterie
(Wiley Online Library, 2019)The practical application of clean energy conversion and storage technologies, such as fuel cells and metal–air batteries, have been significantly impeded by the high cost and scarcity of precious metal catalysts used for ... -
Modification of polyethylene terephthalate track etched membranes by planar magnetron sputtered Ti/TiO2 thin films
(Elsevier, 2021)This study investigates the surface modification of polyethylene terephthalate track-etched membranes by planar magnetron sputtering of titanium and titanium dioxide thin films to improve its hydrophilicity and photocatalytic ... -
Molecularly imprinted polypyrrole sensors for the detection of pyrene in aqueous solutions
(Springer Nature, 2021)Recently, electrochemical sensors have emerged as tools for polyaromatic hydrocarbons (PAH) detection that are cost-effective, easy to produce and use, highly selective and sensitive, and with good reproducibility. Polypyrrole ... -
Multi-objective optimization of a metal hydride reactor coupled with phase change materials for fast hydrogen sorption time
(Journal of Energy Storage, 2023)Recently, the utilization of phase change materials (PCM) for the heat storage/recovery of the metal hydride's reaction heat has received increasing attention. However, the poor heat management process makes hydrogen ... -
Multi-objective optimization of a metal hydride reactor coupled with phase change materials for fast hydrogen sorption time
(Elsevier, 2023)Recently, the utilization of phase change materials (PCM) for the heat storage/recovery of the metal hydride's reaction heat has received increasing attention. However, the poor heat management process makes hydrogen ... -
Nanostructured europium-doped layered lithium manganese oxide as a prospective cathode material for aqueous lithium-ion battery
(Elsevier, 2023)As the world moves to greener and renewable energy generation technologies, scientific researchers are facing a great challenge of concurrently developing energy storage materials with a low production cost, environmentally ... -
Nanostructured silicon derived from an agricultural residue bagasse ash via magnesiothermic reduction method
(MDPI, 2023)This study presents the magnesiothermic reduction of silica into silicon. This reduction process occurs at a lower reaction temperature than its carbothermal counterpart. Furthermore, silica was extracted from sugarcane ... -
New imino-pyridyl nickel (II) complexes: synthesis, molecular structures and application as Heck coupling catalysts
(Elsevier, 2012)Reactions of imino-pyridyl ligands, (2-pyridyl-2-thiophenemethyl)imine (L1) and (2-pyridyl-2-thiopheneethyl)imine (L2) with NiBr2(DME) gave the corresponding complexes [Ni(L1)Br2] (1) and [Ni(L2)Br2] (2) in good yields. ... -
New palladium(II) and platinum(II) complexes based on pyrrole Schiff bases: synthesis, characterization, X-ray structure, and anticancer activity
(American Chemical Society, 2020)New palladium (Pd)II and platinum (Pt)II complexes (C1−C5) from the Schiff base ligands, R-(phenyl)methanamine (L1), R-(pyridin-2-yl)methanamine (L2), and R-(furan2-yl)methanamine (L3) (R-(E)-N-((1H-pyrrol-2-yl) methylene)) ... -
New phenylene bridged binuclear bis (imino-quinolyl) palladium(II) complexes: synthesis, characterization and Heck reactions
(Elsevier, 2012)Two new phenylene bridged binuclear bis(imino-quinolyl) palladium (II) complexes were prepared from the reaction of the ligand 1,4-bis(imino-quinolyl)benzene, L1 with either Pd(cod)Cl2 or Pd(cod)ClMe. The molecular structure ... -
New protocols for the synthesis of 5-amino-7-(4-phenyl)-4,7-dihydro-[1,2,4]triazolo[1,5-a]pyrimidine-6-carboxylate esters using an efficient additive
(TUBITAK, 2020)This work introduces a new additive named 4,4’-trimethylenedipiperidine for the practical and ecofriendly preparation of ethyl 5-amino-7-(4-phenyl)-4,7-dihydro-[1,2,4]triazolo[1,5-a]pyrimidine-6-carboxylate derivatives. ... -
A new vanadium (III) complex of 2,6-Bis(3,5-diphenylpyrazol- 1-ylmethyl)pyridine as a catalyst for ethylene polymerization
(MDPI, 2013)The tridentate ligand 2,6-bis(3,5-diphenylpyrazol-1-ylmethyl)pyridine, abbreviated as 2,6-[(3,5-ph2pz-CH2)2-py], a new pyridine-pyrazole derivative, was prepared from 2,6-bis(bromomethyl)pyridine and 3,5-diphenylpyrazole. ... -
Nickel contamination analysis at cost-effective silver printed paper-based electrodes based on carbon black dimethylglyoxime ink as electrode modifier
(International Association of Physical Chemists, 2022)Electrochemical detection of metal cations at paper-based sensors has been suggested as an attractive alternative to current spectroscopic and chromatographic detection techniques due to the ease of ... -
Novel heterojunction superstrate Cu2ZnInS4−x (CZIS) thin film kesterite solar cell with vertical arrays of hexagonal ZnO nanorods window layer
(Elsevier, 2022-11-24)Quaternary Cu2ZnInS4−x (CZIS) thin films have been prepared by a facile and cheap sol-gel spin coating technique. Low-temperature solution-based methods were used to fabricate a heterojunction solar cell in the superstrate ... -
Occurrences, levels and risk assessment studies of emergingpollutants (pharmaceuticals, perfluoroalkyl and endocrine disruptingcompounds) infish samples from Kalk Bay harbour, South Africa
(Elsevier, 2019)A comprehensive analysis of 15 target chemical compounds (pharmaceuticals and personal care product,perfluoroalkyl compounds and industrial chemicals) were carried out to determine their concentrationsin selected commercially ... -
On the design of smart parking networks in the smart cities: an optimal sensor placement model
(MDPI, 2015)Smart parking is a typical IoT application that can benefit from advances in sensor, actuator and RFID technologies to provide many services to its users and parking owners of a smart city. This paper considers a smart ... -
Oxidation of benzoin catalyzed by oxovanadium (IV) schiff base complexes
(Chemistry Central, 2013)BACKGROUND: The oxidative transformation of benzoin to benzil has been accomplished by the use of a wide variety of reagents or catalysts and different reaction procedures. The conventional oxidizing agents yielded ...