Dichlorido-[(2-diphenylphosphino-benzylidene)-2-methylphenylen-amine]palladium( II) acetonitrile monosolvate

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Date
2013
Author
Motswainyana, William M.
Onani, Martin O.
Jacobs, Jeroen
van Meervelt, Luc
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Abstract
The title imino–phosphine compound, [PdCl2(C26H22NP)] - CH3CN, was prepared by reaction of N-[2-(diphenylphosphanyl) benzylidene]-2-methylaniline with dichlorido(cycloocta- 1,5-diene)palladium(II) in dry CH2Cl2. The PdII cation is coordinated by the P and N atoms of the bidentate chelating ligand and by two chloride anions, generating a distorted square-planar coordination geometry. There is a detectable trans influence for the chloride ligands. The methyl group present in this structure has an influence on the crystal packing.
URI
http://hdl.handle.net/10566/752
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